Transition Metal-Freeipso-Functionalization of Arylboronic Acids and Derivatives
نویسندگان
چکیده
منابع مشابه
Metal-free oxidative cross-coupling of diazirines with arylboronic acids.
We report herein a metal-free cross-coupling of diazirines with arylboronic acids under oxidative conditions. The reaction affords a series of substituted olefins. It is proposed that the interaction between the nitrogen on diazirine with arylboronic acid plays a key role in this transformation.
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SYNTHESIS 2011, No. 20, pp 3209–3219xx.xx.2011 Advanced online publication: 07.09.2011 DOI: 10.1055/s-0030-1260212; Art ID: E69311SS © Georg Thieme Verlag Stuttgart · New York Abstract: The direct functionalization of pyridine and related azine derivatives through carbon–carbon bond-forming reactions is reviewed. Various transformations that use a variety of transitionmetal catalysts are covere...
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xv Chapter
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Transition metal-catalyzed addition of arylboronic acids to 2-formylbenzoates afforded 3-substituted phthalides. By using SPINOL-based phosphites as ligands, a Rh(I)-catalyzed asymmetric version of such an addition reaction was achieved.
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ژورنال
عنوان ژورنال: Advanced Synthesis & Catalysis
سال: 2014
ISSN: 1615-4150
DOI: 10.1002/adsc.201400305